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Brian Williams, not shown, program manager for the Dan River Basin Association, scoops up coal ash on his canoe paddle from the bank of the Dan River as state and federal environmental officials continued their investigations of a spill of coal ash in Eden, N.C., Wednesday, Feb. 5, 2014. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Gerry Broome)

Brian Williams, not shown, program manager for the Dan River Basin Association, scoops up coal ash on his canoe paddle from the bank of the Dan River as state and federal environmental officials continued their investigations of a spill of coal ash in Eden, N.C., Wednesday, Feb. 5, 2014. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Gerry Broome)

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