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Demonstrators hold signs and chant during a protest near Duke Energy's headquarters in Charlotte, N.C., Thursday, Feb. 6, 2014 over Duke Energy's coal plants. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Chuck Burton)

Demonstrators hold signs and chant during a protest near Duke Energy's headquarters in Charlotte, N.C., Thursday, Feb. 6, 2014 over Duke Energy's coal plants. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Chuck Burton)

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