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Demonstrators chant and hold signs behind a display of coal ash and the chemicals in it during a protest near Duke Energy's headquarters in Charlotte, N.C., Thursday, Feb. 6, 2014 over Duke Energy's coal plants. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Chuck Burton)

Demonstrators chant and hold signs behind a display of coal ash and the chemicals in it during a protest near Duke Energy's headquarters in Charlotte, N.C., Thursday, Feb. 6, 2014 over Duke Energy's coal plants. Duke Energy estimates that up to 82,000 tons of ash has been released from a break in a 48-inch storm water pipe at the Dan River Power Plant on Sunday. (AP Photo/Chuck Burton)

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